Hi palino1,
it seems you wish to do two things:
* Create a new material whose liquid transport coefficients are "generated", using a measured A-value and a measured free saturation as input parameters
* Use this material in a simulated absorption experiment to check whether the liquid transport coefficients generated in this way reproduce the measured A-value
The first item is almost independent of w(80%), the second item is completely independent of w(80%).
The formula which WUFI uses to compute the generated liquid transport coefficients only has two parameters: the A-value and the free saturation (see the topic Reference | Material Data | Liquid Transport Coefficients in the help file). WUFI also asks for the Reference Water Content w(80%), but this parameter does not affect the shape of the resulting curve, it only determines the starting point of the curve. You can check this by entering different values for w(80%) and watching the curve diagram.
Below w(80%) the liquid transport coefficients are assumed to be zero. So your choice of w(80%) only affects the resulting curve in a minor way, in particular if w(80%) is markedly smaller than free saturation. In this case the choice of its value only affects the behavior in the region of small water contents and not the high water contents where most of the action in an absorption experiment is.
And concerning the simulated absorption experiment: The absorption of liquid water is determined by the water contents only and is independent of which relative humidities correspond to which water contents. That is, it is independent of the moisture storage function.
As an example, the following diagrams show the results of simulated absorption experiments performed on Baumberger sandstone. In the first simulation the original Baumberger moisture storage function was used, in the other two simulations arbitrarily modified moisture storage functions were used. While the profiles of relative humidity (the green curves) are different, the resulting water contents (the blue curves) are the same after identical simulation periods, and so the resulting A-values are the same as well:
So for the simulation you can use any arbitrary w(80%).
Concerning the interior conditions (the conditions acting on the side of the specimen which is not absorbing the water): The temperature should be the same throughout the specimen, so the temperatures at both surfaces should be set to the same value. The non-absorbing surface of the specimen should be made vapor-tight by applying a very large sd-value (say, 9e9 m) to prevent moisture loss by vapor diffusion through the surface. This de-couples the specimen from the humidity conditions on that side and you may use any arbitrary humidity there.
Regards,
Thomas